List of retained names of inorganic oxoanions

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Retained names for inorganic ions are given, along with the corresponding systematic names, in the 2005 edition of Nomenclature of Inorganic Chemistry (the Red Book).[1] The most important of these are the oxoanions, listed below: other retained names include cyanate for OCN [nitridooxidocarbonate(1−)] and fulminate for the isomeric ONC [carbidooxidonitrate(1−)].[1]

Any common inorganic anion can be named by additive nomenclature to give a systematic name.

Retained name Formula Additive name
Arsonite AsHO22− hydridodioxidoarsenate(2−)
Arsonate AsHO32− hydridotrioxidoarsenate(2−)
Arsinite AsH2O dihydridooxidoarsenate(1−)
Arsinate AsH2O2 dihydridodioxidoarsenate(1−)
Arsenite
Arsorite
AsO33− trioxidoarsenate(3−)
Arsenate
Arsorate
AsO43− tetraoxidoarsenate(3−)
Metaborate (BO2)n catena-poly[(oxidoborate-µ-oxido)(1−)]
Borate BO33− trioxidoborate(3−)
Hypobromite BrO oxidobromate(1−)
Bromite BrO2 dioxidobromate(1−)
Bromate BrO3 trioxidobromate(1−)
Perbromate BrO4 tetraoxidobromate(1−)
Hydrogencarbonate HCO3 hydroxidodioxidocarbonate(1−)
Carbonate CO32− trioxidocarbonate(2−)
Hypochlorite ClO oxidochlorate(1−)
Chlorite ClO2 dioxidochlorate(1−)
Chlorate ClO3 trioxidochlorate(1−)
Perchlorate ClO4 tetraoxidochlorate(1−)
Chromate CrO42− tetraoxidochromate(2−)
Dichromate Cr2O72− µ-oxido-bis(trioxidochromate)(2−)
Phosphonate PHO32− hydridotrioxidophosphate(2−)
Hydrogenphosphite HPO32− hydroxidodioxidophosphate(2−)
Hydrogensulfite HSO3 hydroxidodioxidosulfate(1−)
Hydrogenphosphate HPO42− hydroxidotriioxidophosphate(2−)
Hydrogensulfate HSO4 hydroxidotrioxidosulfate(1−)
Phosphinate PH2O2 dihydridodioxidophosphate(1−)
Dihydrogenborate H2BO3 dihydroxidooxidoborate(1−)
Hydrogenphosphonate PH2O3 hydridohydroxidodioxidophosphate(1−)
Dihydrogenphosphite H2PO3 dihydroxidooxidophosphate(1−)
Dihydrogenphosphate H2PO4 dihydroxidodioxidophosphate(1−)
Diphosphonate P2H2O32− µ-oxido-bis(hydridodioxidophosphate)(2−)
Hypoiodite IO oxidoiodate(1−)
Iodite IO2 dioxidoiodate(1−)
Iodate IO3 trioxidoiodate(1−)
Periodate IO4 tetraoxidoiodate(1−)
Orthoperiodate IO65− hexaoxidoiodate(5−)
Permanganate MnO4 tetraoxidomanganate(1−)
Manganate(VI) MnO42− tetraoxidomanganate(2−)
Manganate(V) MnO43− tetraoxidomanganate(3−)
Nitrite NO2 dioxidonitrate(1−)
Nitrate NO3 trioxidonitrate(1−)
Peroxynitrite NO3 oxidoperoxidonitrate(1−)
Peroxynitrate NO4 dioxidoperoxidonitrate(1−)
Phosphite PO33− trioxidophosphate(3−)
Metaphosphate (PO3)n catena-poly[(dioxidophosphate-µ-oxido)(1−)]
Phosphate PO43− tetraoxidophosphate(3−)
Peroxyphosphate PO53− trioxidoperoxidophosphate(3−)
Hypodiphosphate P2O64− bis(trioxidophosphate)(PP)(4−)
Diphosphate P2O74− µ-oxido-bis(trioxidophosphate)(4−)
Peroxydiphosphate P2O84− µ-peroxido-bis(trioxidophosphate)(4−)
Sulfite SO32− trioxidosulfate(2−)
Sulfate SO42− tetraoxidosulfate(2−)
Peroxysulfate SO52− trioxidoperoxidosulfate(2−)
Thiosulfate S2O32− trioxido-1κ3O-disulfate(SS)(2−)
Dithionite S2O42− bis(dioxidosulfate)(SS)(2−)
Dithionate S2O62− bis(trioxidosulfate)(SS)(2−)
Disulfate S2O72− µ-oxido-bis(trioxidosulfate)(2−)
Peroxydisulfate S2O82− µ-peroxido-1κO,2κO'-bis(trioxidosulfate)(2−)
Tetrathionate S4O62− bis[(trioxidosulfate)sulfate](SS)(2−)
Selenite SeO32− trioxidoselenate(2−)
Selenate SeO42− tetraoxidoselenate(2−)
Metasilicate (SiO32−)n catena-poly[(dioxidosilicate-µ-oxido)(2−)]
Silicate SiO44− tetraoxidosilicate(4−)
Disilicate Si2O76− µ-oxido-bis(trioxidosilicate)(6−)
Tellurate TeO42− tetraoxidotellurate(2−)
Orthotellurate TeO66− hexaoxidotellurate(6−)

References

  1. 1.0 1.1 Table IX. In Nomenclature of Inorganic Chemistry; IUPAC Recommendations 2005; Royal Society of Chemistry: Cambridge, 2005; pp 280–336. ISBN 0-85404-438-8, <http://www.iupac.org/publications/books/rbook/Red_Book_2005.pdf>.
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