Potassium perbromate
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Potassium perbromate | |
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IUPAC name | Potassium perbromate |
Other names | Potassium bromate(VII) |
Identifiers | |
InChI | InChI=1/BrHO4.K/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1 |
InChIKey | VXLUZERCXISKBW-REWHXWOFAE |
Standard InChI | InChI=1S/BrHO4.K/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1 |
Standard InChIKey | VXLUZERCXISKBW-UHFFFAOYSA-M |
CAS number | [ | ]
ChemSpider | |
Properties[1][2] | |
Chemical formula | KBrO4 |
Molar mass | 183.00 g mol−1 |
Melting point |
275–280 °C decomp. |
Solubility in water | ca. 3.7 g/100 g |
Thermochemistry[2] | |
Std enthalpy of formation ΔfH |
−287.6 kJ mol−1 |
Std Gibbs energy of formation ΔfG |
−174.1 kJ mol−1 |
Standard molar entropy S |
170 J K−1 mol−1 |
Related compounds | |
Other anions | Potassium perchlorate Potassium periodate |
Other cations | Lithium perbromate Sodium perbromate Rubidium perbromate Caesium perbromate |
Other compounds | Potassium bromide Potassium hypobromite Potassium bromite Potassium bromate |
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) |
Potassium bromate, KBrO4, is the potassium salt of perbromic acid. It is prepared by the neutralization of perbromic acid with potassium carbonate or potassium hydroxide.[1][3]
Notes and references
Notes
References
- ↑ 1.0 1.1 Ukeles, S. D.; Freiberg, M. Bromine, Inorganic Compounds. In Kirk-Othmer Encyclopedia of Chemical Technology; John Wiley: New York, 2002. DOI: 10.1002/0471238961.021815131001031.
- ↑ 2.0 2.1 Greenwood, Norman N.; Earnshaw, A. Chemistry of the Elements; Pergamon: Oxford, 1984; pp 1020–22. ISBN 0-08-022057-6.
- ↑ Appelman, E. H. Perbromic acid and potassium perbromate. Inorg. Synth. 1972, 13, 1–9. DOI: 10.1002/9780470132449.ch1.
Further reading
- Schreiner, Felix; Osborne, Darrell W.; Pocius, Alphonsus V.; Appelman, Evan H. Heat capacity of potassium perbromate, KBrO4, between 5 and 350°K. Inorg. Chem. 1970, 9 (10), 2320–24. DOI: 10.1021/ic50092a024.
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