Lanthanum

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bariumlanthanumcerium
Y

La

Ac
Atomic properties
Atomic number 57
Standard atomic weight 138.905 47(7)
Electron configuration [Xe] 5d1 6s2
Physical properties[1]
Melting point 920 °C (1193 K)
Boiling point 3420 °C (3693 K)
Density 6.17 g cm−3 (20 °C)
Electric resistivity 57–80 μΩ cm
Chemical properties[1][2]
Electronegativity 1.10 (Pauling)
Solubility in water reacts
Ionization energies[3][4]
1st 5.5770(6) eV
538.10(6) kJ mol−1
2nd 11.06(8) eV
1067(8) kJ mol−1
3rd 19.1759(19) eV
1850.19(18) kJ mol−1
Electron affinity[5]
0.470(20) eV
45.3(19) kJ mol−1
Atomic radii[1][6][7]
Covalent radius 207 pm
Metallic radius 187 pm
Ionic radius 117.2 pm (La3+, Oh)
Thermodynamic properties[1][8]
Standard entropy 56.8 J K−1 mol−1
Enthalpy change of atomization 423(6) kJ mol−1
Enthalpy change of fusion 8.5 kJ mol−1
Enthalpy change of vaporization 402 kJ mol−1
Miscellaneous
CAS number 7439-91-0
EC number 231-099-0
Where appropriate, and unless otherwise stated, data are given for 100 kPa (1 bar) and 298.15 K (25 °C).

Lanthanum (symbol: La) is a chemical element, one of the transition metals and also a lanthanoid and a rare earth element.

Notes and references

Notes

References

  1. 1.0 1.1 1.2 1.3 Greenwood, Norman N.; Earnshaw, A. Chemistry of the Elements; Pergamon: Oxford, 1984; pp 1102–10. ISBN 0-08-022057-6.
  2. Allred, A. L. Electronegativity values from thermochemical data. J. Inorg. Nucl. Chem. 1961, 17 (3–4), 215–21. DOI: 10.1016/0022-1902(61)80142-5.
  3. Martin, W. C.; Zalubas, R.; Hagan, L. Atomic energy levels – the rare earth elements. Natl. Stand. Ref. Data Ser. (U.S., Natl. Bur. Stand.) 1978, 60, 1–411.
  4. Moore, Charlotte E. Ionization potentials and ionization limits derived from the analyses of optical spectra. Natl. Stand. Ref. Data Ser., (U.S. Natl. Bur. Stand.) 1970, 34, 1–22, <http://www.nist.gov/data/nsrds/NSRDS-NBS34.pdf>.
  5. Covington, A. M.; Calabrese, D.; Thompson, J. S.; Kvale, T. J. Measurement of the electron affinity of lanthanum. J. Phys. B: At., Mol. Opt. Phys. 1998, 31 (20), L855–60. DOI: 10.1088/0953-4075/31/20/002.
  6. Cordero, Beatriz; Gómez, Verónica; Platero-Prats, Ana E.; Revés, Marc; Echeverría, Jorge; Cremades, Eduard; Barragán, Flavia; Alvarez, Santiago Covalent radii revisited. Dalton Trans. 2008 (5), 2832–38. DOI: 10.1039/b801115j.
  7. Shannon, R. D. Revised effective ionic radii and systematic studies of interatomic distances in halids and chalcogenides. Acta Crystallogr. A 1976, 32 (5), 751–67. DOI: 10.1107/S0567739476001551.
  8. Jolly, William L. Modern Inorganic Chemistry, 2nd ed.; McGraw-Hill: New York, 1991; p 586. ISBN 0-07-032768-8.

External links

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