Difference between revisions of "Lithium"

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|below = [[Sodium|Na]]
 
|below = [[Sodium|Na]]
 
|atomic-number = 3
 
|atomic-number = 3
|atomic-weight = 6.941(2)
+
|atomic-weight = 6.941(2)<ref group="note">Commercially available lithium materials have atomic weights that range between 6.939 and 6.996; if a more accurate value is required, it must be determined for the specific material.</ref>
 
|configuration = 1s<sup>2</sup> 2s<sup>1</sup>
 
|configuration = 1s<sup>2</sup> 2s<sup>1</sup>
 
|phys-ref = <ref name="NIST">{{NIST chemistry | name = Lithium | id = 1S/Li | accessdate = 2010-06-20}}.</ref>
 
|phys-ref = <ref name="NIST">{{NIST chemistry | name = Lithium | id = 1S/Li | accessdate = 2010-06-20}}.</ref>
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|pictograms = {{GHS02|Water-react. 1}}{{GHS05|Skin Corr. 1B}}
 
|pictograms = {{GHS02|Water-react. 1}}{{GHS05|Skin Corr. 1B}}
 
|signal-word = DANGER
 
|signal-word = DANGER
|hazard-statements = {{H-phrases|260|314}}
+
|hazard-statements = {{H-phrases|260|314}}<ref group="note">EU014</ref>
 
|CAS-number = 7439-93-2
 
|CAS-number = 7439-93-2
 
|EC-number = 231-102-5
 
|EC-number = 231-102-5

Revision as of 13:05, 20 June 2010

heliumlithiumberyllium
H

Li

Na
Atomic properties
Atomic number 3
Standard atomic weight 6.941(2)[note 1]
Electron configuration 1s2 2s1
Physical properties[1]
Melting point 179 °C (452 K)
Boiling point 1317 °C (1590 K)
Chemical properties
Solubility in water reacts
Ionization energies[2]
1st 5.392 eV
520.25 kJ mol−1
2nd 75.638 eV
7298.0 kJ mol−1
3rd 122.451 eV
11 814.7 kJ mol−1
Total 203.481 eV
19 632.9 kJ mol−1
Thermodynamic properties[1][3]
Standard entropy 29.12(20) J K−1 mol−1
Enthalpy change of atomization 159.3(10) kJ mol−1
Entropy change of atomization 138.782(10) J K−1 mol−1
Enthalpy change of fusion 2.38 kJ mol−1
Hazards[4]
GHS pictograms Water-react. 1Skin Corr. 1B
GHS signal word DANGER
GHS hazard statements H260, H314[note 2]
Miscellaneous
CAS number 7439-93-2
EC number 231-102-5
Where appropriate, and unless otherwise stated, data are given for 100 kPa (1 bar) and 298.15 K (25 °C).

Lithium (symbol: Li) is a chemical element, the lightest of the alkali metals.

Notes and references

Notes

  1. Commercially available lithium materials have atomic weights that range between 6.939 and 6.996; if a more accurate value is required, it must be determined for the specific material.
  2. EU014

References

  1. 1.0 1.1 Lithium. In NIST Chemistry WebBook; National Institute for Standards and Technology, <http://webbook.nist.gov/cgi/inchi/InChI%3D1S/Li>. (accessed 20 June 2010).
  2. CRC Handbook of Chemistry and Physics, 62nd ed.; Weast, Robert C., Ed.; CRC Press: Boca Raton, FL, 1981; p E-65. ISBN 0-8493-0462-8.
  3. Cox, J. D.; Wagman, D. D.; Medvedev, V. A. CODATA Key Values for Thermodynamics; Hemisphere: New York, 1989. ISBN 0891167587, <http://www.codata.org/resources/databases/key1.html>.
  4. Index no. 003-001-00-4 of Annex VI, Part 3, to Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. OJEU L353, 31.12.2008, pp 1–1355 at p 340.

External links

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