Difference between revisions of "Lutetium"

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|electronegativity = 1.27 (Pauling)
 
|electronegativity = 1.27 (Pauling)
 
|solubility = reacts
 
|solubility = reacts
|IE-ref = <ref>{{citation | last1 = Martin | first1 = W. C. | last2 = Zalubas | first2 = R. | last3 = Hagan | first3 = L. | title = Atomic energy levels – the rare earth elements | journal =
+
|IE-ref = <ref name="G&E"/><ref>{{NSRDS-NBS 60}}.</ref><ref>{{NSRDS-NBS 34}}.</ref>
Natl. Stand. Ref. Data Ser. (U.S., Natl. Bur. Stand.) | year = 1978 | volume = 60 | pages = 1–411}}.</ref>
 
 
|IE1 = 5.425 85(2) eV<br/>523.51(2) kJ mol<sup>−1</sup>
 
|IE1 = 5.425 85(2) eV<br/>523.51(2) kJ mol<sup>−1</sup>
|IE2 = 13.90 eV<br/>1341 kJ mol<sup>−1</sup>
+
|IE2 = 13.9(4) eV<br/>1340 kJ mol<sup>−1</sup>
 
|IE3 = 21.29 eV<br/>2054 kJ mol<sup>−1</sup>
 
|IE3 = 21.29 eV<br/>2054 kJ mol<sup>−1</sup>
 
|EA-ref = <ref>{{citation | last1 = Davis | first1 = V. T. | last2 = Thompson | first2 = J. S. | title = Measurement of the electron affinity of lutetium | journal = J. Phys. B: At., Mol. Opt. Phys. | year = 2001 | volume = 34 | issue = 14 | pages = L433–37 | doi = 10.1088/0953-4075/34/14/102}}.</ref>
 
|EA-ref = <ref>{{citation | last1 = Davis | first1 = V. T. | last2 = Thompson | first2 = J. S. | title = Measurement of the electron affinity of lutetium | journal = J. Phys. B: At., Mol. Opt. Phys. | year = 2001 | volume = 34 | issue = 14 | pages = L433–37 | doi = 10.1088/0953-4075/34/14/102}}.</ref>

Latest revision as of 19:42, 27 December 2010

ytterbiumlutetiumhafnium


Lu

Lr
Atomic properties
Atomic number 71
Standard atomic weight 174.9668(1)
Electron configuration [Xe] 4f14 5d1 6s2
Physical properties[1]
Melting point 1652 °C (1925 K)
Boiling point 3327 °C (3600 K)
Density 9.84 g cm−3 (20 °C)
Electric resistivity 68 μΩ cm
Chemical properties[1][2]
Electronegativity 1.27 (Pauling)
Solubility in water reacts
Ionization energies[1][3][4]
1st 5.425 85(2) eV
523.51(2) kJ mol−1
2nd 13.9(4) eV
1340 kJ mol−1
3rd 21.29 eV
2054 kJ mol−1
Electron affinity[5]
0.340(10) eV
32.8(10) kJ mol−1
Atomic radii[1][6][7]
Covalent radius 187 pm
Metallic radius 173.8 pm
Ionic radius 100.1 pm (Lu3+, Oh)
Thermodynamic properties[1]
Enthalpy change of vaporization 414 kJ mol−1
Miscellaneous
CAS number 7439-94-3
EC number 231-103-0
Where appropriate, and unless otherwise stated, data are given for 100 kPa (1 bar) and 298.15 K (25 °C).

Lutetium (symbol: Lu) is a chemical element, one of the lanthanoids and also a rare earth element.

Notes and references

Notes

References

  1. 1.0 1.1 1.2 1.3 1.4 Greenwood, Norman N.; Earnshaw, A. Chemistry of the Elements; Pergamon: Oxford, 1984; pp 1423–49. ISBN 0-08-022057-6.
  2. Allred, A. L. Electronegativity values from thermochemical data. J. Inorg. Nucl. Chem. 1961, 17 (3–4), 215–21. DOI: 10.1016/0022-1902(61)80142-5.
  3. Martin, W. C.; Zalubas, R.; Hagan, L. Atomic energy levels – the rare earth elements. Natl. Stand. Ref. Data Ser. (U.S., Natl. Bur. Stand.) 1978, 60, 1–411.
  4. Moore, Charlotte E. Ionization potentials and ionization limits derived from the analyses of optical spectra. Natl. Stand. Ref. Data Ser., (U.S. Natl. Bur. Stand.) 1970, 34, 1–22, <http://www.nist.gov/data/nsrds/NSRDS-NBS34.pdf>.
  5. Davis, V. T.; Thompson, J. S. Measurement of the electron affinity of lutetium. J. Phys. B: At., Mol. Opt. Phys. 2001, 34 (14), L433–37. DOI: 10.1088/0953-4075/34/14/102.
  6. Cordero, Beatriz; Gómez, Verónica; Platero-Prats, Ana E.; Revés, Marc; Echeverría, Jorge; Cremades, Eduard; Barragán, Flavia; Alvarez, Santiago Covalent radii revisited. Dalton Trans. 2008 (5), 2832–38. DOI: 10.1039/b801115j.
  7. Shannon, R. D. Revised effective ionic radii and systematic studies of interatomic distances in halids and chalcogenides. Acta Crystallogr. A 1976, 32 (5), 751–67. DOI: 10.1107/S0567739476001551.

External links

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