Difference between revisions of "Uranium"

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|IE-ref = <ref>{{Kaye&Laby | contribution = Ionization potentials | chapter = 4.1.2 | accessdate = 2011-04-14 | url = http://www.kayelaby.npl.co.uk/atomic_and_nuclear_physics/4_1/4_1_2.html}}.</ref>
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|StdInChIkey = JFALSRSLKYAFGM-UHFFFAOYSA-N
 
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'''Uranium''' (symbol: '''U''') is a member of the [[actinoid]] series of [[chemical element]]s.
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'''Uranium''' (symbol: '''U''') is a [[chemical element]], a member of the [[actinoid]] series. Although all [[isotope]]s of uranium are [[Radioactivity|unstable]], three have sufficiently long [[Half-life|half-lives]] that a substantial amount of primordial uranium has survived since the formation of the Solar System. The natural material is only very slightly radioactive, and uranium and its compounds have a number of commercial uses, although some precautions must be taken over its decay products.
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Uranium was identified as a new element in 1789 by [[Martin Heinrich Klaproth]], and named after the planet Uranus, which had been discovered by William Herschel in 1781. Its chemistry resembles that of [[molybdenum]] and [[tungsten]], with a preponderance of the +4 and +6 [[oxidation state]]s, and [[periodic table]]s from before the Second World War often placed uranium as a [[transition metal]].
  
 
==Notes and references==
 
==Notes and references==

Latest revision as of 07:15, 21 April 2011

protactiniumuraniumneptunium
Nd

U

Atomic properties
Atomic number 92
Standard atomic weight 238.028 91(3)
Electron configuration [Rn] 5f3 6d1 7s2
Physical properties[1][2]
Melting point 1130 °C (1400 K)
Boiling point 3930 °C (4200 K)
Density 19.05 g cm−3
Electric resistivity 28 × 10−6 Ω cm
Chemical properties[3]
Electronegativity 1.38 (Pauling)
Ionization energy[4]
6.19 eV,
597 kJ mol−1
Atomic radii[1][5][6]
Covalent radius 196 pm
Metallic radius 156 pm
Ionic radius 87 pm (U6+, Oh)
103 pm (U4+, Oh)
Thermodynamic properties[1][7]
Standard entropy 50.20(20) J K−1 mol−1
Enthalpy change of atomization 533(8) kJ mol−1
Entropy change of atomization 149.59(22) J K−1 mol−1
Enthalpy change of fusion 12.6 kJ mol−1
Enthalpy change of vaporization 417 kJ mol−1
Hazards[8]
GHS pictograms Acute Tox. 2STOT RE 2
GHS signal word DANGER
GHS hazard statements H330, H300, H373, H413
Miscellaneous
CAS number 7440-61-1
EC number 231-170-6
Where appropriate, and unless otherwise stated, data are given for 100 kPa (1 bar) and 298.15 K (25 °C).

Uranium (symbol: U) is a chemical element, a member of the actinoid series. Although all isotopes of uranium are unstable, three have sufficiently long half-lives that a substantial amount of primordial uranium has survived since the formation of the Solar System. The natural material is only very slightly radioactive, and uranium and its compounds have a number of commercial uses, although some precautions must be taken over its decay products.

Uranium was identified as a new element in 1789 by Martin Heinrich Klaproth, and named after the planet Uranus, which had been discovered by William Herschel in 1781. Its chemistry resembles that of molybdenum and tungsten, with a preponderance of the +4 and +6 oxidation states, and periodic tables from before the Second World War often placed uranium as a transition metal.

Notes and references

Notes

References

  1. 1.0 1.1 1.2 Greenwood, Norman N.; Earnshaw, A. Chemistry of the Elements; Pergamon: Oxford, 1984; pp 1450–86. ISBN 0-08-022057-6.
  2. Electrical resistivities. In Kaye & Laby Tables of Physical & Chemical Constants, 16th ed., 1995; Chapter 2.6.1, <http://www.kayelaby.npl.co.uk/general_physics/2_6/2_6_1.html>. (accessed 4 April 2011).
  3. Allred, A. L. Electronegativity values from thermochemical data. J. Inorg. Nucl. Chem. 1961, 17 (3–4), 215–21. DOI: 10.1016/0022-1902(61)80142-5.
  4. Ionization potentials. In Kaye & Laby Tables of Physical & Chemical Constants, 16th ed., 1995; Chapter 4.1.2, <http://www.kayelaby.npl.co.uk/atomic_and_nuclear_physics/4_1/4_1_2.html>. (accessed 14 April 2011).
  5. Cordero, Beatriz; Gómez, Verónica; Platero-Prats, Ana E.; Revés, Marc; Echeverría, Jorge; Cremades, Eduard; Barragán, Flavia; Alvarez, Santiago Covalent radii revisited. Dalton Trans. 2008 (5), 2832–38. DOI: 10.1039/b801115j.
  6. Shannon, R. D. Revised effective ionic radii and systematic studies of interatomic distances in halids and chalcogenides. Acta Crystallogr. A 1976, 32 (5), 751–67. DOI: 10.1107/S0567739476001551.
  7. Cox, J. D.; Wagman, D. D.; Medvedev, V. A. CODATA Key Values for Thermodynamics; Hemisphere: New York, 1989. ISBN 0891167587, <http://www.codata.org/resources/databases/key1.html>.
  8. Index no. 092-001-00-8 of Annex VI, Part 3, to Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. OJEU L353, 31.12.2008, pp 1–1355 at p 446.

Further reading

External links

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