Difference between revisions of "Plutonium"

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|EA-ref =  
 
|EA-ref =  
 
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|thermo-ref =  
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|thermo-ref = <ref name="Clark"/><ref>{{citation | last1 = Oetting | first1 = F. L. | last2 = Rand | first2 = M. H. | last3 = Ackerman | first3 = R. J. | title = The Chemical Thermodynamics of Actinide Elements and Compounds | volume = 1 | year = 1976 | publisher = IAEA | location = Vienna | isbn = 9201490763}}.</ref>
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|entropy = 50.5 J K<sup>−1</sup> mol<sup>−1</sup>
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|entropy =
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|enthalpy-vaporization = 394(25) kJ mol<sup>−1</sup>
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|enthalpy-vaporization = 347.7(21) kJ mol<sup>−1</sup>
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|entropy-vaporization = 97(13) J K<sup>−1</sup> mol<sup>−1</sup>
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|entropy-vaporization =  
 
|enthalpy-atomization =  
 
|enthalpy-atomization =  
 
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|enthalpy-fusion = 5.19 kJ mol<sup>−1</sup>
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|enthalpy-fusion = 2.73(10) kJ mol<sup>−1</sup>
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|heat-capacity = 29.6 J K<sup>−1</sup> mol<sup>−1</sup>
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|heat-capacity = 31.6 J K<sup>−1</sup> mol<sup>−1</sup>
 
|radius-ref = <ref name="G&E">{{Greenwood&Earnshaw1st|pages=1450–86}}.</ref><ref>{{Cordero et al. (2008)}}.</ref><ref>{{Shannon (1976)}}.</ref>
 
|radius-ref = <ref name="G&E">{{Greenwood&Earnshaw1st|pages=1450–86}}.</ref><ref>{{Cordero et al. (2008)}}.</ref><ref>{{Shannon (1976)}}.</ref>
 
|metallic-radius = 159 pm
 
|metallic-radius = 159 pm
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|StdInChIkey = OYEHPCDNVJXUIW-UHFFFAOYSA-N
 
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'''Plutonium''' (symbol: '''Pu''') is a [[chemical element]], a member of the [[actinoid]] series. All [[isotope]]s of plutonium are [[Radioactivity|unstable]], with [[Half-life|half-lives]] of less than 81&nbsp;million years:<ref>{{Nubase 2003}}.</ref> any plutonium that was present at the formation of the Solar System has long since decayed, although trace amounts of plutonium are naturally formed by the capture of [[neutron]]s by [[uranium-238]].<ref>{{citation | last1 = Peppard | first1 = D. F. | last2 = Mason | first2 = G. W. | last3 = Gray | first3 = P. R. | last4 = Mech | first4 = J. F. | title = Occurrence of the (4n + 1) Series in Nature | journal = J. Am. Chem. Soc. | year = 1952 | volume = 74 | pages = 6081–84 | doi = 10.1021/ja01143a074}}.</ref> Apart from these traces, plutonium is prepared artificially in [[nuclear reactor]]s: about 2000&nbsp;tonnes of plutonium has been prepared in this way.<ref>Albright, D. and Kramer, K. (2004) B. Atom. Sci., 60(6), 14–16.</ref>
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'''Plutonium''' (symbol: '''Pu''') is a [[chemical element]], a member of the [[actinoid]] series. All [[isotope]]s of plutonium are [[Radioactivity|unstable]]: trace amounts of the longest-lived isotope, [[plutonium-244]] (''t''<sub>½</sub>&nbsp;= 80.0(9){{e|6}}&nbsp;a) have been found in [[bastnasite]] ores,<ref>{{citation | last1 = Hoffman | first1 = D. C. | last2 = Lawrence | first2 = F. O. | last3 = Mewherter | first3 = J. L. | last4 = Rourke | first4 = F. M. | title = Detection of Plutonium-244 in Nature | journal = Nature | year =  1971 | volume = 234 | pages = 132–34 | doi = 10.1038/234132a0}}.</ref> and trace amounts of [[plutonium-239]] (''t''<sub>½</sub>&nbsp;= 24.11(3){{e|3}}&nbsp;a) are naturally formed by the capture of [[neutron]]s by [[uranium-238]].<ref>{{citation | last1 = Seaborg | first1 = Glenn T. | authorlink1 = Glenn T. Seaborg | last2 = Perlman | first2 = Morris L. | title = Search for Elements 94 and 93 in Nature. Presence of 94<sup>239</sup> in Pitchblende | journal = J. Am. Chem. Soc. | year = 1948 | volume = 70 | issue = 4 | pages = 1571–73 | doi = 10.1021/ja01184a083}}.</ref><ref>{{citation | last1 = Garner | first1 = C. S. | last2 = Bonner | first2 = N. A. | last3 = Seaborg | first3 = G. T. | authorlink3 = Glenn T. Seaborg | title = Search for Elements 94 and 93 in Nature. Presence of 94<sup>239</sup> in Carnotite | journal = J. Am. Chem. Soc. | year = 1948 | volume = 70 | issue = 10 | pages = 3453–54 | doi = 10.1021/ja01190a069}}.</ref> Apart from these traces, plutonium is prepared artificially in [[nuclear reactor]]s: about 2000&nbsp;tonnes has been prepared in this way.<ref>{{citation | last1 = Albright | first1 = David | last2 = Kramer | first2 = Kimberly | title = Fissile Material: Stockpiles Still Growing | journal = Bull. At. Sci. | year = 2004 | volume = 60 | issue = 6 | pages = 14–16 | doi = 10.2968/060006005}}.</ref>
  
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Plutonium was first prepared in 1940  by [[Glenn Seaborg]] and [[Edwin McMillan]] at the [[University of California Radiation Laboratory]], by the [[deuteron]] bombardment of [[uranium-238]].<ref>Seaborg, G. T., Wahl, A. C., and Kennedy, J. W. (1946) Phys. Rev., 69, 367.</ref> It was named after the planet Pluto, by analogy with [[uranium]], named after the planet Uranus, and [[neptunium]], named after the planet Neptune.<ref>Seaborg, G. T. and Wahl, A. C. (1948) J. Am. Chem. Soc., 70(3), 1128–34.</ref>
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Plutonium was first prepared in 1940  by [[Glenn T. Seaborg|Glenn Seaborg]] and [[Edwin McMillan]] at the [[University of California Radiation Laboratory]], by the [[deuteron]] bombardment of uranium-238.<ref>{{citation | last1 = Seaborg | first1 = G. T. | authorlink1 = Glenn T. Seaborg | last2 = Wahl | first2 = A. C. | last3 = Kennedy | first3 = J. W. | title = Radioactive Element 94 from Deuterons on Uranium | journal = Phys. Rev. | year = 1946 | volume = 69 | issue = 7–8 | page = 367 | doi = 10.1103/PhysRev.69.367}}.</ref> It was named after the planet Pluto, by analogy with [[uranium]], named after the planet Uranus, and [[neptunium]], named after the planet Neptune.<ref>{{citation | last1 = Seaborg | first1 = Glenn T. | authorlink1 = Glenn T. Seaborg | last2 = Wahl | first2 = Arthur C. | title = The Chemical Properties of Elements 94 and 93 | journal = J. Am. Chem. Soc. | year = 1948 | volume = 70 | issue = 3 | pages = 1128–34 | doi = 10.1021/ja01183a076}}.</ref>
  
 
==Notes and references==
 
==Notes and references==

Latest revision as of 09:59, 24 April 2011

neptunium ← plutonium → americium
Sm
↑
Pu
↓
—
Atomic properties
Atomic number 94
Electron configuration [Rn] 5f6 7s2
Physical properties[1][2][3]
Melting point 640 °C (913 K)
Boiling point 3230 °C (3500 K)
Density 19.86 g cm−3
Electric resistivity 146 × 10−6 Ω cm
Chemical properties[4]
Electronegativity 1.28 (Pauling)
Ionization energy[5]
6.0258(2) eV,
581.40(2) kJ mol−1
Atomic radii[2][6][7]
Covalent radius 187 pm
Metallic radius 159 pm
Ionic radius 85 pm (Pu6+, Oh)
100 pm (Pu4+, Oh)
Thermodynamic properties[1][8]
Enthalpy change of fusion 2.73(10) kJ mol−1
Enthalpy change of vaporization 347.7(21) kJ mol−1
Molar heat capacity (Cp) 31.6 J K−1 mol−1
Miscellaneous
CAS number 7440-07-5
EC number 231-117-7
Where appropriate, and unless otherwise stated, data are given for 100 kPa (1 bar) and 298.15 K (25 °C).
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Plutonium (symbol: Pu) is a chemical element, a member of the actinoid series. All isotopes of plutonium are unstable: trace amounts of the longest-lived isotope, plutonium-244 (t½ = 80.0(9) × 106 a) have been found in bastnasite ores,[9] and trace amounts of plutonium-239 (t½ = 24.11(3) × 103 a) are naturally formed by the capture of neutrons by uranium-238.[10][11] Apart from these traces, plutonium is prepared artificially in nuclear reactors: about 2000 tonnes has been prepared in this way.[12]

Plutonium was first prepared in 1940 by Glenn Seaborg and Edwin McMillan at the University of California Radiation Laboratory, by the deuteron bombardment of uranium-238.[13] It was named after the planet Pluto, by analogy with uranium, named after the planet Uranus, and neptunium, named after the planet Neptune.[14]

Notes and references

Notes

References

  1. ↑ 1.0 1.1 Clark, David L.; Hecker, Siegfried S.; Jarvinen, Gordon D.; Neu, Mary P. Plutonium. In The Chemistry of the Actinide and Transactinide Elements, 3rd ed.; Morss, Lester R.; Edelstein, Norman M.; Fuger, Jean, Eds.; Springer: Dordrecht, the Netherlands, 2006; Vol. 2, Chapter 7, pp 813–1264. doi:10.1007/1-4020-3598-5_7, <http://radchem.nevada.edu/classes/rdch710/files/plutonium.pdf>.
  2. ↑ 2.0 2.1 Greenwood, Norman N.; Earnshaw, A. Chemistry of the Elements; Pergamon: Oxford, 1984; pp 1450–86. ISBN 0-08-022057-6.
  3. ↑ Electrical resistivities. In Kaye & Laby Tables of Physical & Chemical Constants, 16th ed., 1995; Chapter 2.6.1, <http://www.kayelaby.npl.co.uk/general_physics/2_6/2_6_1.html>. (accessed 4 April 2011).
  4. ↑ Allred, A. L. Electronegativity values from thermochemical data. J. Inorg. Nucl. Chem. 1961, 17 (3–4), 215–21. DOI: 10.1016/0022-1902(61)80142-5.
  5. ↑ Köhler, S.; Deißenberger, R.; Eberhardt, K.; Erdmann, N.; Herrmann, G.; Huber, G.; Kratz, J. V.; Nunnemann, M., et al. Determination of the first ionization potential of actinide elements by resonance ionization mass spectroscopy. Spectrochim. Acta, Part B 1997, 52 (6), 717–26. DOI: 10.1016/S0584-8547(96)01670-9.
  6. ↑ Cordero, Beatriz; Gómez, Verónica; Platero-Prats, Ana E.; Revés, Marc; Echeverría, Jorge; Cremades, Eduard; Barragán, Flavia; Alvarez, Santiago Covalent radii revisited. Dalton Trans. 2008 (5), 2832–38. DOI: 10.1039/b801115j.
  7. ↑ Shannon, R. D. Revised effective ionic radii and systematic studies of interatomic distances in halids and chalcogenides. Acta Crystallogr. A 1976, 32 (5), 751–67. DOI: 10.1107/S0567739476001551.
  8. ↑ Oetting, F. L.; Rand, M. H.; Ackerman, R. J. The Chemical Thermodynamics of Actinide Elements and Compounds; IAEA: Vienna, 1976; Vol. 1. ISBN 9201490763.
  9. ↑ Hoffman, D. C.; Lawrence, F. O.; Mewherter, J. L.; Rourke, F. M. Detection of Plutonium-244 in Nature. Nature 1971, 234, 132–34. DOI: 10.1038/234132a0.
  10. ↑ Seaborg, Glenn T.; Perlman, Morris L. Search for Elements 94 and 93 in Nature. Presence of 94239 in Pitchblende. J. Am. Chem. Soc. 1948, 70 (4), 1571–73. DOI: 10.1021/ja01184a083.
  11. ↑ Garner, C. S.; Bonner, N. A.; Seaborg, G. T. Search for Elements 94 and 93 in Nature. Presence of 94239 in Carnotite. J. Am. Chem. Soc. 1948, 70 (10), 3453–54. DOI: 10.1021/ja01190a069.
  12. ↑ Albright, David; Kramer, Kimberly Fissile Material: Stockpiles Still Growing. Bull. At. Sci. 2004, 60 (6), 14–16. DOI: 10.2968/060006005.
  13. ↑ Seaborg, G. T.; Wahl, A. C.; Kennedy, J. W. Radioactive Element 94 from Deuterons on Uranium. Phys. Rev. 1946, 69 (7–8), 367. DOI: 10.1103/PhysRev.69.367.
  14. ↑ Seaborg, Glenn T.; Wahl, Arthur C. The Chemical Properties of Elements 94 and 93. J. Am. Chem. Soc. 1948, 70 (3), 1128–34. DOI: 10.1021/ja01183a076.

Further reading

  • Lemire, R. J.; Fuger, J.; Nitsche, H.; Potter, P.; Rand, M. H.; Rydberg, J.; Spahiu, K.; Sullivan, J. C., et al. Chemical Thermodynamics of Neptunium and Plutonium; Elsevier: Amsterdam, 2001. ISBN 044450379X.

External links

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