Difference between revisions of "Scandium"

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Line 13: Line 13:
 
|boiling-point = 2748 °C (3021 K)
 
|boiling-point = 2748 °C (3021 K)
 
|density = 3.0 g cm<sup>−3</sup> (20&nbsp;°C)
 
|density = 3.0 g cm<sup>−3</sup> (20&nbsp;°C)
 +
|resistivity = 50–61 μΩ cm
 
|chem-ref = <ref name="G&E"/><ref>{{Allred (1961)}}.</ref>
 
|chem-ref = <ref name="G&E"/><ref>{{Allred (1961)}}.</ref>
 
|electronegativity = 1.36 (Pauling)
 
|electronegativity = 1.36 (Pauling)
Line 25: Line 26:
 
|entropy = 34.6 J K<sup>−1</sup> mol<sup>−1</sup>
 
|entropy = 34.6 J K<sup>−1</sup> mol<sup>−1</sup>
 
|enthalpy-vaporization = 332.71 kJ mol<sup>−1</sup>
 
|enthalpy-vaporization = 332.71 kJ mol<sup>−1</sup>
 +
|enthalpy-atomization = 376(20) kJ mol<sup>−1</sup>
 
|entropy-atomization =  
 
|entropy-atomization =  
 
|enthalpy-fusion = 15.77 kJ mol<sup>−1</sup>
 
|enthalpy-fusion = 15.77 kJ mol<sup>−1</sup>
|radius-ref = &#32;<ref>{{Cordero et al. (2008)}}.</ref><ref>{{Shannon (1976)}}.</ref>
+
|radius-ref = <ref name="G&E"/><ref>{{Cordero et al. (2008)}}.</ref><ref>{{Shannon (1976)}}.</ref>
 +
|metallic-radius = 162 pm
 
|covalent-radius = 170 pm
 
|covalent-radius = 170 pm
 
|ionic-radius = 88.5 pm (Sc<sup>3+</sup>, ''O<sub>h</sub>'')
 
|ionic-radius = 88.5 pm (Sc<sup>3+</sup>, ''O<sub>h</sub>'')

Revision as of 13:58, 26 December 2010

calciumscandiumtitanium


Sc

Y
Atomic properties
Atomic number 21
Standard atomic weight 44.955 912(6)
Electron configuration [Ar] 3d1 4s2
Physical properties[1]
Melting point 1539 °C (1812 K)
Boiling point 2748 °C (3021 K)
Density 3.0 g cm−3 (20 °C)
Electric resistivity 50–61 μΩ cm
Chemical properties[1][2]
Electronegativity 1.36 (Pauling)
Solubility in water reacts
Ionization energy[3]
6.561 44(6) eV
633.083(6) kJ mol−1
Electron affinity[4]
0.189(20) eV
18.2(19) kJ mol−1
Atomic radii[1][5][6]
Covalent radius 170 pm
Metallic radius 162 pm
Ionic radius 88.5 pm (Sc3+, Oh)
Thermodynamic properties[1][7]
Standard entropy 34.6 J K−1 mol−1
Enthalpy change of atomization 376(20) kJ mol−1
Enthalpy change of fusion 15.77 kJ mol−1
Enthalpy change of vaporization 332.71 kJ mol−1
Miscellaneous
CAS number 7440-20-2
EC number 231-129-2
Where appropriate, and unless otherwise stated, data are given for 100 kPa (1 bar) and 298.15 K (25 °C).

Scandium (symbol: Sc) is a chemical element, the lightest of the transition metals.

Notes and references

Notes

References

  1. 1.0 1.1 1.2 1.3 Greenwood, Norman N.; Earnshaw, A. Chemistry of the Elements; Pergamon: Oxford, 1984; pp 1102–10. ISBN 0-08-022057-6.
  2. Allred, A. L. Electronegativity values from thermochemical data. J. Inorg. Nucl. Chem. 1961, 17 (3–4), 215–21. DOI: 10.1016/0022-1902(61)80142-5.
  3. Kaufman, V.; Sugar, J. Wavelengths and energy level classifications of scandium spectra for all stages of ionization. J. Phys. Chem. Ref. Data 1988, 17 (4), 1679–1790. DOI: doi:10.1063/1.555815.
  4. Feigerle, C. S.; Herman, Z.; Lineberger, W. C. Laser Photoelectron Spectroscopy of Sc and Y: A Determination of the Order of Electron Filling in Transition Metal Anions. J. Electron Spectrosc. Relat. Phenom. 1981, 23 (3), 441–50. DOI: 10.1016/0368-2048(81)85050-5.
  5. Cordero, Beatriz; Gómez, Verónica; Platero-Prats, Ana E.; Revés, Marc; Echeverría, Jorge; Cremades, Eduard; Barragán, Flavia; Alvarez, Santiago Covalent radii revisited. Dalton Trans. 2008 (5), 2832–38. DOI: 10.1039/b801115j.
  6. Shannon, R. D. Revised effective ionic radii and systematic studies of interatomic distances in halids and chalcogenides. Acta Crystallogr. A 1976, 32 (5), 751–67. DOI: 10.1107/S0567739476001551.
  7. Jolly, William L. Modern Inorganic Chemistry, 2nd ed.; McGraw-Hill: New York, 1991; p 589. ISBN 0-07-032768-8.

External links

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