Difference between revisions of "Oxygen"

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|chem-ref = <ref>{{citation | first = A. L. | last = Allred | title = Electronegativity values from thermochemical data | journal = J. Inorg. Nucl. Chem. | year = 1961 | volume = 17 | issue = 3–4 | page = 215–21 | doi = 10.1016/0022-1902(61)80142-5}}.</ref>
 
|chem-ref = <ref>{{citation | first = A. L. | last = Allred | title = Electronegativity values from thermochemical data | journal = J. Inorg. Nucl. Chem. | year = 1961 | volume = 17 | issue = 3–4 | page = 215–21 | doi = 10.1016/0022-1902(61)80142-5}}.</ref>
 
|electronegativity = 3.44 (Pauling)
 
|electronegativity = 3.44 (Pauling)
|IE-ref = <ref name="NIST-Oat">{{NIST chemistry | name = Oxygen, atomic | id = 1S/O | accessdate = 2010-03-15}}.</ref>
+
|IE-ref = <ref name="NIST-Oat">{{NIST chemistry | name = Oxygen, atomic | id = 1S/O | accessdate = 2010-03-15}}.</ref><ref>{{CODATA 2002}}.</ref>
|IE1 = 13.618 06 eV, 1313.943 kJ mol<sup>−1</sup>
+
|IE1 = 13.618 06 eV,<br/>1313.943 kJ mol<sup>−1</sup>
|IE2 = 35.1211 eV, 3388.67 kJ mol<sup>−1</sup>
+
|IE2 = 35.1211 eV,<br/>3388.67 kJ mol<sup>−1</sup>
|IE3 = 54.9355 eV, 5300.47 kJ mol<sup>−1</sup>
+
|IE3 = 54.9355 eV,<br/>5300.47 kJ mol<sup>−1</sup>
|IE4 = 77.4135 eV
+
|IE4 = 77.4135 eV,<br/>7469.27 kJ mol<sup>−1</sup>
|IE5 = 113.8989 eV
+
|IE5 = 113.8989 eV,<br/>10 989.57 kJ mol<sup>−1</sup>
|IE6 = 138.1196 eV
+
|IE6 = 138.1196 eV,<br/>13 326.52 kJ mol<sup>−1</sup>
|IE7 = 739.3268 eV
+
|IE7 = 739.3268 eV,<br/>71 334.20 kJ mol<sup>−1</sup>
|IE8 = 871.4097 eV
+
|IE8 = 871.4097 eV,<br/>84 078.26 kJ mol<sup>−1</sup>
|IE-total = 2043.8432 eV
+
|IE-total = 2043.8432 eV,<br/>197 200.9 kJ mol<sup>−1</sup>
 
|EA-ref = <ref name="NIST-Oat"/>
 
|EA-ref = <ref name="NIST-Oat"/>
 
|EA1 = 140.9759(42) kJ mol<sup>−1</sup>
 
|EA1 = 140.9759(42) kJ mol<sup>−1</sup>

Revision as of 16:47, 15 March 2010

nitrogenoxygenfluorine


O

S
Atomic properties
Atomic number 8
Standard atomic weight 15.9994(3)
Electron configuration [He] 2s2 2p4
Physical properties (O2)[1]
Melting point 54.8(2) K (−218.8 °C)
Boiling point 90.2(2) K (−183.0 °C)
Critical point 154.58 K, 50.43 bar
Chemical properties[2]
Electronegativity 3.44 (Pauling)
Ionization energies[3][4]
1st 13.618 06 eV,
1313.943 kJ mol−1
2nd 35.1211 eV,
3388.67 kJ mol−1
3rd 54.9355 eV,
5300.47 kJ mol−1
4th 77.4135 eV,
7469.27 kJ mol−1
5th 113.8989 eV,
10 989.57 kJ mol−1
6th 138.1196 eV,
13 326.52 kJ mol−1
7th 739.3268 eV,
71 334.20 kJ mol−1
8th 871.4097 eV,
84 078.26 kJ mol−1
Total 2043.8432 eV,
197 200.9 kJ mol−1
Electron affinity[3]
140.9759(42) kJ mol−1
Atomic radii
Covalent radius 66 pm
Van der Waals radius 152 pm
Thermodynamic properties (O2)[1]
Standard entropy 205.152(5) J K−1 mol−1
Enthalpy change of fusion 0.444 kJ mol−1
Enthalpy change of vaporization 6.82 kJ mol−1
Molar heat capacity (Cp) 29.378 J K−1 mol−1
Miscellaneous
CAS number 7782-44-7 (O2)
17778-80-2 (atomic)
EC number 231-956-9
Where appropriate, and unless otherwise stated, data are given for 100 kPa (1 bar) and 298.15 K (25 °C).

Oxygen (ˈɒksɨdʒɨn) is a colourless gas which makes up about one fifth of the Earth's atmosphere. Its name comes from the Greek ὀξύς (oxys; acid, literally "sharp", from the taste of acids) and -γενής (-genēs; producer, literally "begetter").

References

  1. 1.0 1.1 Oxygen. In NIST Chemistry WebBook; National Institute for Standards and Technology, <http://webbook.nist.gov/cgi/inchi/InChI%3D1S/O2/c1-2>. (accessed 15 March 2010).
  2. Allred, A. L. Electronegativity values from thermochemical data. J. Inorg. Nucl. Chem. 1961, 17 (3–4), 215–21. DOI: 10.1016/0022-1902(61)80142-5.
  3. 3.0 3.1 Oxygen, atomic. In NIST Chemistry WebBook; National Institute for Standards and Technology, <http://webbook.nist.gov/cgi/inchi/InChI%3D1S/O>. (accessed 15 March 2010).
  4. Mohr, Peter J.; Taylor, Barry N. CODATA recommended values of the fundamental physical constants: 2002. Rev. Mod. Phys. 2005, 77 (1), 1–107. DOI: 10.1103/RevModPhys.77.1.

External links

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