Fermium

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Er

Fm

Atomic properties
Atomic number 100
Electron configuration [Rn] 5f12 6s2
Physical properties[1][Note 1]
Melting point 1125 K (850 °C)
Chemical properties[Note 1]
Electronegativity 1.3 (Pauling)
Ionization energy
6.50 eV
627 kJ mol−1
Atomic radii[1][2][3][Note 1]
Metallic radius 196 pm
Ionic radius 92 pm (Fm3+)
Thermodynamic properties[1]
Enthalpy change of atomization 142(13) kJ mol−1
Entropy change of atomization 98(13) J K−1 mol−1
Miscellaneous
CAS number 7440-72-4
Where appropriate, and unless otherwise stated, data are given for 100 kPa (1 bar) and 298.15 K (25 °C).

Fermium (symbol: Fm) is a synthetic chemical element and a member of the actinoid series. It is the heaviest element than can be formed by neutron bombardment of lighter elements, and hence the last element that can be prepared in macroscopic quantities.

Discovery

Notes and references

Notes

  1. 1.0 1.1 1.2 Many of the properties of fermium are only known through estimation and/or extrapolation. The melting point and metallic radius were estimated on the basis of the enthalpy change of atomization and comparison with divalent lanthanoids; the electronegativity was estimated on the basis of periodic trends; the ionic radius was estimated from the behaviour of Fm3+ α-hydroxyisobutyrate (α-HIB) complexes on ion exchange complexes, and agrees well with theoretical calculations. The lectron configuration and thermodynamic properties are directly measured.

References

  1. 1.0 1.1 1.2 Haire, Richard G.; Gibson, John K. The enthalpy of sublimation and thermodynamic functions of fermium. J. Chem. Phys. 1989, 91 (11), 7085–96. DOI: 10.1063/1.457326.
  2. David, F.; Samhoun, K.; Guillaumont, R.; Edelstein, N. Thermodynamic properties of 5f elements. J. Inorg. Nucl. Chem. 1978, 40 (1), 69–74. DOI: 10.1016/0022-1902(78)80309-1.
  3. Brüchle, W.; Schädel, M.; Scherer, U. W.; Kratz, J. V.; Gregorich, K. E.; Lee, D.; Nurmia, M.; Chasteler, R. M., et al. The hydration enthalpies of Md3+ and Lr3+. Inorg. Chim. Acta 1988, 146 (2), 267–76. DOI: 10.1016/S0020-1693(00)80619-2.

Further reading

External links

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