Americium

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plutoniumamericiumcurium
Eu

Am

Atomic properties
Atomic number 95
Electron configuration [Rn] 5f7 7s2
Physical properties[1][2][3]
Melting point 876(5) °C (1149(5) K)
Boiling point 2067 °C (2340 K)
Density 13.671 g cm−3
Electric resistivity 68 × 10−6 Ω cm
Chemical properties[4]
Electronegativity 1.3 (Pauling)
Ionization energies[5][6]
1st 5.9738(2) eV,
576.38(2) kJ mol−1
2nd 12.5 eV
1206 kJ mol−1
3rd 18.8 eV
1814 kJ mol−1
Atomic radii[2][7][8]
Covalent radius 180 pm
Metallic radius 173 pm
Ionic radius 85 pm (Am4+, Oh)
97.5 pm (Am3+, Oh)
121 pm (Am2+, Oh)
Thermodynamic properties[1][9]
Standard entropy 55 J K−1 mol−1
Enthalpy change of fusion 14.4 kJ mol−1
Enthalpy change of vaporization 230.2 kJ mol−1
Molar heat capacity (Cp) 25.5 J K−1 mol−1
Miscellaneous
CAS number 7440-35-9
EC number 231-144-4
Where appropriate, and unless otherwise stated, data are given for 100 kPa (1 bar) and 298.15 K (25 °C).

Americium (symbol: Am) is a synthetic chemical element, a member of the actinoid series.

Notes and references

Notes

References

  1. 1.0 1.1 Runde, Wolfgang H.; Schulz, Wallace W. Americium. In The Chemistry of the Actinide and Transactinide Elements, 3rd ed.; Morss, Lester R.; Edelstein, Norman M.; Fuger, Jean, Eds.; Springer: Dordrecht, the Netherlands, 2006; Vol. 3, Chapter 8, pp 1265–1395. doi:10.1007/1-4020-3598-5_8, <http://radchem.nevada.edu/classes/rdch710/files/americium.pdf>.
  2. 2.0 2.1 Greenwood, Norman N.; Earnshaw, A. Chemistry of the Elements; Pergamon: Oxford, 1984; pp 1450–86. ISBN 0-08-022057-6.
  3. Electrical resistivities. In Kaye & Laby Tables of Physical & Chemical Constants, 16th ed., 1995; Chapter 2.6.1, <http://www.kayelaby.npl.co.uk/general_physics/2_6/2_6_1.html>. (accessed 4 April 2011).
  4. Pauling, Linus The Nature of the Chemical Bond, 3rd ed.; Ithaca, NY, 1960. ISBN 0-8014-0333-2.
  5. Deissenberger, Rüdiger; Köhler, Stefan; Ames, Friedhelm; Eberhardt, Klaus; Erdmann, Nicole; Funk, Heike; Herrmann, Günter; Kluge, Heinz-Jürgen, et al. First Determination of the Ionization Potential of Americium and Curium. Angew. Chem., Int. Ed. Engl. 1995, 34 (7), 814–15. DOI: 10.1002/anie.199508141.
  6. Carlson, Thomas A.; Nestor, C. W., Jr.; Wasserman, Neil; Mcdowell, J. D. Calculated ionization potentials for multiply charged ions. At. Data Nucl. Data Tables 1970, 2, 63–99. DOI: 10.1016/S0092-640X(70)80005-5.
  7. Cordero, Beatriz; Gómez, Verónica; Platero-Prats, Ana E.; Revés, Marc; Echeverría, Jorge; Cremades, Eduard; Barragán, Flavia; Alvarez, Santiago Covalent radii revisited. Dalton Trans. 2008 (5), 2832–38. DOI: 10.1039/b801115j.
  8. Shannon, R. D. Revised effective ionic radii and systematic studies of interatomic distances in halids and chalcogenides. Acta Crystallogr. A 1976, 32 (5), 751–67. DOI: 10.1107/S0567739476001551.
  9. Oetting, F. L.; Rand, M. H.; Ackerman, R. J. The Chemical Thermodynamics of Actinide Elements and Compounds; IAEA: Vienna, 1976; Vol. 1. ISBN 9201490763.

External links

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