Difference between revisions of "Berkelium"

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|atomic-number = 97
 
|atomic-number = 97
 
|configuration = [Rn] 5f<sup>9</sup> 7s<sup>2</sup>
 
|configuration = [Rn] 5f<sup>9</sup> 7s<sup>2</sup>
|phys-ref =  
+
|phys-ref = <ref name="Peterson">Peterson et al., 1971</ref>
 
|melting-point = 1259 K (986 °C)
 
|melting-point = 1259 K (986 °C)
|density =  
+
|density = 14.78 g cm<sup>−3</sup>
 
|chem-ref = <ref>{{Pauling3rd}}.</ref>
 
|chem-ref = <ref>{{Pauling3rd}}.</ref>
 
|electronegativity = 1.3 (Pauling)
 
|electronegativity = 1.3 (Pauling)
|IE-ref =  
+
|IE-ref = <ref name="Köhler">{{citation | first1 = S. | last1 = Köhler | first2 = R. | last2 = Deißenberger | first3 = K. | last3 = Eberhardt | first4 = N. | last4 = Erdmann | first5 = G. | last5 = Herrmann | first6 = G. | last6 = Huber | first7 = J. V. | last7 = Kratz | first8 = M. | last8 = Nunnemann | first9 = G. | last9 = Passler | first10 = P. M. | last10 = Rao | first11 = J. | last11 = Riegel | first12 = N. | last12 = Trautmann | first13 = K. | last13 = Wendt | title = Determination of the first ionization potential of actinide elements by resonance ionization mass spectroscopy | journal = Spectrochim. Acta, Part B | volume = 52 | issue = 6 | year = 1997 | pages = 717–26 | doi = 10.1016/S0584-8547(96)01670-9}}.</ref><ref name="Erdmann">{{citation | first1 = N. | last1 = Erdmann | first2 = M. | last2 = Nunnemann | first3 = K. | last3 = Eberhardt | first4 = G. | last4 = Herrmann | first5 = G. | last5 = Huber | first6 = S. | last6 = Köhler | first7 = J. V. | last7 = Kratz | first8 = G. | last8 = Passler | first9 = J. R. | last9 = Peterson | first10 = N. | last10 = Trautmann | first11 = A. | last11 = Waldek | title = Determination of the first ionization potential of nine actinide elements by resonance ionization mass spectroscopy (RIMS) | journal = J. Alloys Compd. | volume = 271–273 | year = 1998 | pages = 837–40 | doi = 10.1016/S0925-8388(98)00229-1}}.</ref>
|IE1 = 6.26 eV<br/>601 kJ mol<sup>−1</sup>
+
|IE1 = 6.1979(2) eV<br/>598.01(2) kJ mol<sup>−1</sup>
|radius-ref =  
+
|radius-ref = <ref name="Peterson"/>
|metallic-radius =  
+
|metallic-radius = 170 pm
 
|ionic-radius = 110 pm (Bk<sup>3+</sup>, ''O<sub>h</sub>'')<br/>97 pm (Bk<sup>4+</sup>, ''O<sub>h</sub>'')
 
|ionic-radius = 110 pm (Bk<sup>3+</sup>, ''O<sub>h</sub>'')<br/>97 pm (Bk<sup>4+</sup>, ''O<sub>h</sub>'')
|thermo-ref =  
+
|thermo-ref = <ref>Ward and Hill, 1976</ref><ref>Ward et al., 1982</ref>
|enthalpy-atomization = 142(13) kJ mol<sup>−1</sup>
+
|entropy = 76.2(13) J K<sup>−1</sup> mol<sup>−1</sup>
|entropy-atomization = 98(13) J K<sup>−1</sup> mol<sup>−1</sup>
+
|enthalpy-atomization = 310(6) kJ mol<sup>−1</sup>
 +
|enthalpy-fusion = 7.92 kJ mol<sup>−1</sup>
 
|misc-ref =  
 
|misc-ref =  
 
|CAS-number = 7440-40-6
 
|CAS-number = 7440-40-6

Revision as of 06:48, 26 September 2010

curiumberkeliumcalifornium
Tb

Bk

Atomic properties
Atomic number 97
Electron configuration [Rn] 5f9 7s2
Physical properties[1]
Melting point 1259 K (986 °C)
Density 14.78 g cm−3
Chemical properties[2]
Electronegativity 1.3 (Pauling)
Ionization energy[3][4]
6.1979(2) eV
598.01(2) kJ mol−1
Atomic radii[1]
Metallic radius 170 pm
Ionic radius 110 pm (Bk3+, Oh)
97 pm (Bk4+, Oh)
Thermodynamic properties[5][6]
Standard entropy 76.2(13) J K−1 mol−1
Enthalpy change of atomization 310(6) kJ mol−1
Enthalpy change of fusion 7.92 kJ mol−1
Miscellaneous
CAS number 7440-40-6
Where appropriate, and unless otherwise stated, data are given for 100 kPa (1 bar) and 298.15 K (25 °C).

Berkelium (symbol: Bk) is a synthetic chemical element and a member of the actinoid series. It is named after the city of Berkeley, California, the location of the University of California Radiation Laboratory where it was discovered in 1949.

Notes and references

Notes

References

  1. 1.0 1.1 Peterson et al., 1971
  2. Pauling, Linus The Nature of the Chemical Bond, 3rd ed.; Ithaca, NY, 1960. ISBN 0-8014-0333-2.
  3. Köhler, S.; Deißenberger, R.; Eberhardt, K.; Erdmann, N.; Herrmann, G.; Huber, G.; Kratz, J. V.; Nunnemann, M., et al. Determination of the first ionization potential of actinide elements by resonance ionization mass spectroscopy. Spectrochim. Acta, Part B 1997, 52 (6), 717–26. DOI: 10.1016/S0584-8547(96)01670-9.
  4. Erdmann, N.; Nunnemann, M.; Eberhardt, K.; Herrmann, G.; Huber, G.; Köhler, S.; Kratz, J. V.; Passler, G., et al. Determination of the first ionization potential of nine actinide elements by resonance ionization mass spectroscopy (RIMS). J. Alloys Compd. 1998, 271–273, 837–40. DOI: 10.1016/S0925-8388(98)00229-1.
  5. Ward and Hill, 1976
  6. Ward et al., 1982

External links

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