Difference between revisions of "Protactinium"

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(Created page with "{{Infobox element |name = protactinium |symbol = Pa |left = thorium |right = uranium |above = Pr |below = — |atomic-number = 91 |configuration = [Rn] 5...")
 
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|below = —
 
|below = —
 
|atomic-number = 91
 
|atomic-number = 91
|configuration = [Rn] 5f<sup>2</sup> 6d<sup>1</sup> 7s<sup>2</sup> {{#tag:ref| The configuration {{nowrap|[Rn] 5f<sup>1</sup> 6d<sup>2</sup> 7s<sup>2</sup>}} is given as a possible alternative in some textbooks.|group=note}}
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|atomic-weight = 231.035 88(2)
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|configuration = [Rn] 5f<sup>2</sup> 6d<sup>1</sup> 7s<sup>2</sup> {{#tag:ref|The configuration {{nowrap|[Rn] 5f<sup>1</sup> 6d<sup>2</sup> 7s<sup>2</sup>}} is given as a possible alternative in some textbooks.|group=note}}
 
|phys-ref = <ref name="MKT">{{citation | last1 = Myasoedov | first1 = Boris F. | last2 = Kirby | first2 = H. W. | last3 = Tananaev | first3 = Ivan G. | contribution = Protactinium | title = The Chemistry of the Actinide and Transactinide Elements | editor1-first = Lester R. | editor1-last = Morss | editor2-first = Norman M. | editor2-last = Edelstein | editor3-first = Jean | editor3-last = Fuger | edition = 3rd | year = 2006 | volume = 1 | publisher = Springer | location = Dordrecht, the Netherlands | chapter = 4 | pages = 161–252 | url = http://radchem.nevada.edu/classes/rdch710/files/protactinium.pdf | doi = 10.1007/1-4020-3598-5_4}}.</ref><ref name="G&E">{{Greenwood&Earnshaw1st|pages=1450–86}}.</ref>
 
|phys-ref = <ref name="MKT">{{citation | last1 = Myasoedov | first1 = Boris F. | last2 = Kirby | first2 = H. W. | last3 = Tananaev | first3 = Ivan G. | contribution = Protactinium | title = The Chemistry of the Actinide and Transactinide Elements | editor1-first = Lester R. | editor1-last = Morss | editor2-first = Norman M. | editor2-last = Edelstein | editor3-first = Jean | editor3-last = Fuger | edition = 3rd | year = 2006 | volume = 1 | publisher = Springer | location = Dordrecht, the Netherlands | chapter = 4 | pages = 161–252 | url = http://radchem.nevada.edu/classes/rdch710/files/protactinium.pdf | doi = 10.1007/1-4020-3598-5_4}}.</ref><ref name="G&E">{{Greenwood&Earnshaw1st|pages=1450–86}}.</ref>
 
|melting-point = 1565(19)&nbsp;°C (1838&nbsp;K)
 
|melting-point = 1565(19)&nbsp;°C (1838&nbsp;K)

Revision as of 15:14, 13 April 2011

thoriumprotactiniumuranium
Pr

Pa

Atomic properties
Atomic number 91
Standard atomic weight 231.035 88(2)
Electron configuration [Rn] 5f2 6d1 7s2 [note 1]
Physical properties[1][2]
Melting point 1565(19) °C (1838 K)
Boiling point ca. 4227 °C (4500 K)
Density 15.37(8) g cm−3
Electric resistivity 19.1 × 10−6 Ω cm
Ionization energy[3]
5.89(12) eV
568(12) kJ mol−1
Atomic radii[1][4][5]
Covalent radius 200 pm
Metallic radius 163 pm
Ionic radius 92 pm (Pa5+, Oh)
Thermodynamic properties[2]
Enthalpy change of fusion 16.7 kJ mol−1
Enthalpy change of vaporization 481 kJ mol−1
Miscellaneous
CAS number 7440-13-3
Where appropriate, and unless otherwise stated, data are given for 100 kPa (1 bar) and 298.15 K (25 °C).

Protactinium (symbol: Pa) is a member of the actinoid series of chemical elements.

Notes and references

Notes

  1. The configuration [Rn] 5f1 6d2 7s2 is given as a possible alternative in some textbooks.

References

  1. 1.0 1.1 Myasoedov, Boris F.; Kirby, H. W.; Tananaev, Ivan G. Protactinium. In The Chemistry of the Actinide and Transactinide Elements, 3rd ed.; Morss, Lester R.; Edelstein, Norman M.; Fuger, Jean, Eds.; Springer: Dordrecht, the Netherlands, 2006; Vol. 1, Chapter 4, pp 161–252. doi:10.1007/1-4020-3598-5_4, <http://radchem.nevada.edu/classes/rdch710/files/protactinium.pdf>.
  2. 2.0 2.1 Greenwood, Norman N.; Earnshaw, A. Chemistry of the Elements; Pergamon: Oxford, 1984; pp 1450–86. ISBN 0-08-022057-6.
  3. Sugar, Jack Ionization energies of the neutral actinides. J. Chem. Phys. 1973, 59, 788–91. DOI: 10.1063/1.1680091. Sugar, Jack Revised ionization energies of the neutral actinides. J. Chem. Phys. 1974, 60, 4103. DOI: 10.1063/1.1680874.
  4. Cordero, Beatriz; Gómez, Verónica; Platero-Prats, Ana E.; Revés, Marc; Echeverría, Jorge; Cremades, Eduard; Barragán, Flavia; Alvarez, Santiago Covalent radii revisited. Dalton Trans. 2008 (5), 2832–38. DOI: 10.1039/b801115j.
  5. Shannon, R. D. Revised effective ionic radii and systematic studies of interatomic distances in halids and chalcogenides. Acta Crystallogr. A 1976, 32 (5), 751–67. DOI: 10.1107/S0567739476001551.

External links